SIMBAD references

Our observations of TMC-1 with the Yebes 40m radio telescope in the 31.0-50.3GHz range allowed us to detect a group of unidentified lines, showing a complex line pattern indicative of an open-shell species. The observed frequencies of these lines and the similarity of the spectral pattern with that of the 2_0,2-1_0,1 rotational transition of H₂CCN indicate that the lines arise from the deuterated cyanomethyl radical, HDCCN. Using Fourier transform microwave spectroscopy experiments combined with electric discharges, we succeeded in producing the radical HDCCN in the laboratory and observed its 1_0,1-0_0,0 and 2_0,2-1_0,1 rotational transitions. From our observations and assuming a rotational temperature of 5K, we derive an abundance ratio H₂CCN/HDCCN=20±4. The high abundance of the deuterated form of H₂CCN is well accounted for by a standard gas-phase model, in which deuteration is driven by deuteron transfer from the H₂D⁺ molecular ion.