2022A&A...660L...6C -
Astronomy and Astrophysics, volume 660, L6-6 (2022/4-1)
The ALMA-PILS survey: First tentative detection of 3-hydroxypropenal (HOCHCHCHO) in the interstellar medium and chemical modeling of the C3H4O2 isomers.
COUTENS A., LOISON J.-C., BOULANGER A., CAUX E., MULLER H.S.P., WAKELAM V., MANIGAND S. and JORGENSEN J.K.
Abstract (from CDS):
Characterizing the molecular composition of solar-type protostars is useful for improving our understanding of the physico-chemical conditions under which the Sun and its planets formed. In this work, we analyzed the Atacama Large Millimeter/submillimeter Array (ALMA) data of the Protostellar Interferometric Line Survey (PILS), an unbiased spectral survey of the solar-type protostar IRAS 16293-2422, and we tentatively detected 3-hydroxypropenal (HOCHCHCHO) for the first time in the interstellar medium towards source B. Based on the observed line intensities and assuming local thermodynamic equilibrium, its column density is constrained to be ∼10
15 cm
–2, corresponding to an abundance of 10
–4 relative to methanol, CH
3OH. Additional spectroscopic studies are needed to constrain the excitation temperature of this molecule. We included HOCHCHCHO and five of its isomers in the chemical network presented in Manigand et al. (
2021A&A...645A..53M) and we predicted their chemical evolution with the Nautilus code. The model reproduces the abundance of HOCHCHCHO within the uncertainties. This species is mainly formed through the grain surface reaction CH
2CHO + HCO - HCOCH
2CHO, followed by the tautomerization of HCOCH
2CHO into HOCHCHCHO. Two isomers, CH
3COCHO and CH
2COHCHO, are predicted to be even more abundant than HOCHCHCHO. Spectroscopic studies of these molecules are essential in searching for them in IRAS 16293-2422 and other astrophysical sources.
Abstract Copyright:
© A. Coutens et al. 2022
Journal keyword(s):
astrochemistry - stars: formation - stars: protostars - ISM: molecules - ISM: individual objects: IRAS 16293-2422
Simbad objects:
3
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