2005A&A...433..535F

We have carried out a molecular survey of the Class 0 IM protostar NGC 7129 - FIRS 2 (hereafter FIRS 2) and the Herbig Be star LkHα 234 with the aim of studying the chemical evolution of the envelopes of intermediate-mass (IM) young stellar objects (YSOs). The two objects have similar luminosities (∼500L_☉) and are located in the same molecular cloud which minimizes the chemical differences due to different stellar masses or initial cloud conditions. Moreover, since they are located at the same distance, we have the same spatial resolution in both objects. A total of 17 molecular species (including rare isotopes) have been observed in both objects and the structure of their envelopes and outflows has been determined with unprecedent detail. Our results show that the protostellar envelopes are dispersed and warmed up during the evolution of the YSO into a pre-main sequence star. In fact, the envelope mass decreases by a factor >5 from FIRS 2 to LkHα 234, while the kinetic temperature increases from ∼13K to 28K. On the other hand, there is no molecular outflow associated with LkHα 234. The molecular outflow seems to stop before the star becomes visible. These physical changes strongly affect the chemistry of their envelopes. The N₂H⁺ and NH₃ abundances seem to be quite similar in the two objects. However, the H¹³CO⁺ abundance is a factor of ∼3 lower in the densest part of FIRS 2 than in LkHα 234, very likely because of depletion. In contrast, the SiO abundance is larger by a factor of ∼100 in FIRS 2 than in LkHα 234. CS presents complex behavior since its emission arises in different envelope components (outflow, cold envelope, hot core) and could also suffer from depletion. The CH₃OH and H₂CO column densities are very similar in FIRS 2 and LkHα 234 which implies that the beam-averaged abundances are a factor >5 larger in LkHα 234 than in FIRS 2. The same is found for the PDR tracers CN and HCN which have similar column densities in both objects. Finally, complex behavior is found for the deuterated compounds. While the DCO⁺/H¹³CO⁺ ratio decreases by a factor of ∼4 from FIRS 2 to LkHα 234, the D₂CO/H₂CO ratios is within a factor 1.5 in both objects. The detection of a warm CH₃CN component with T_k>63K shows the existence of a hot core in FIRS 2. Thus far, only a handful of hot cores have been detected in low and intermediate mass stars. Based on our results in FIRS 2 and LkHα 234, we propose some abundance ratios that can be used as chemical clocks for the envelopes of IM YSOs. The SiO/CS, CN/N₂H⁺, HCN/N₂H⁺, DCO⁺/HCO⁺ and D₂CO/DCO⁺ ratios are good diagnostics of the protostellar evolutionary stage.